Journal of organometallic chemistry

Dehydrogenative coupling of primary alkyl silanes using Wilkinson's catalyst

L Rosenberg, DN Kobus

Index: Rosenberg, Lisa; Kobus, Danielle N. Journal of Organometallic Chemistry, 2003 , vol. 685, # 1-2 p. 107 - 112

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Abstract

Primary alkyl silanes (RSiH3, where R= n-C12H25 or n-C8H17) undergo dehydrogenative coupling in the presence of (Ph3P) 3RhCl (1) to give oligomeric products. 29Si {1H}-NMR and gel permeation chromatography suggest that chains of up to 5–6 silicons are forming in these reactions. Variations in product distributions observed for these two substrates, of supposedly comparable Si H reactivity, may be correlated with the relative rates of ...