Beyond aresta's complex: Ni-and Pd-catalyzed organozinc coupling with CO2
CS Yeung, VM Dong
Index: Yeung, Charles S.; Dong, Vy M. Journal of the American Chemical Society, 2008 , vol. 130, # 25 p. 7826 - 7827
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Citation Number: 175
Abstract
Organozinc reagents are widely used in organic synthesis due primarily to their high functional group compatibility. However, under mild conditions, these organometallic reagents do not react directly with CO2, the ideal C1 source for organic synthesis. Herein, we report that both Ni and Pd complexes can catalyze the addition of organozinc reagents to CO2 under mild conditions (1 atm CO2, 0° C). This transformation represents an important ...
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