A phen–terpy conjugate whose chelate coordination axes are orthogonal to one another and its zinc complex
B Champin, V Sartor, JP Sauvage
Index: Champin, Benoit; Sartor, Valerie; Sauvage, Jean-Pierre New Journal of Chemistry, 2006 , vol. 30, # 1 p. 22 - 25
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Citation Number: 11
Abstract
A new highly rigid ditopic ligand has been prepared which consists of a terpy fragment connected through its 4′ position to the 3 position of a phen nucleus via a 1, 4-phenylene linker. The chemical structure of the presently reported two-chelate ligand is such that the coordination axes of the two chelates are orthogonal to one another. The reaction of this phen–terpy conjugate with Zn2+ affords in good yield a dimeric structure, as shown by ES- ...
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