Desulfinylation of prop-2-enesulfinic acid: Experimental results and mechanistic theoretical analysis

A Varela-Alvarez, D Markovic, P Vogel…

Index: Fokin, Andrey A.; Yurchenko, Alexander G.; Rodionov, Vladimir N.; Gunchenko, Pavel A.; Yurchenko, Raisa I.; Reichenberg, Armin; Wiesner, Jochen; Hintz, Martin; Jomaa, Hassan; Schreiner, Peter R. Organic Letters, 2007 , vol. 9, # 21 p. 4379 - 4382

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Citation Number: 29

Abstract

... g ... with C−Y bond formation and allylic rearrangement (demonstrated for X = Y: ArSO 2 N═S═O, SO 2 , SeO 2 , CO 2 , N 2 , H ... involves formation of reactive intermediates in which the H-transfer might not be the rate determining step (observed for X = Y: 1 O 2 , R′CON═NCOR ...