Synthesis

A Stereoselective Synthesis of (Z)-3-Aryl and Alkylmethylidene-1H-isoindolin-1-ones

M Lamblin, A Couture, E Deniau, P Grandclaudon

Index: Lamblin, Marc; Couture, Axel; Deniau, Eric; Grandclaudon, Pierre Synthesis, 2006 , # 8 p. 1333 - 1338

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Citation Number: 14

Abstract

Abstract A series of Z-configured (hetero) aryl and alkylmethylideneisoindolin-1-ones has been efficiently prepared by treatment of N-methoxycarbonylisoindolin-1-ones with a base and reaction with selected aldehydes. The parent N-acylated isoindolin-1-ones have been assembled by a Parham-type cyclization of N-(2-iodoarylmethyl) dicarbamates.

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