Regio-and enantioselective properties of the lipase-catalyzed irreversible transesterification of some 2-substituted-1, 4-butanediols in organic solvents
P Ferraboschi, S Casati, E Verza, E Santaniello
Index: Ferraboschi, Patrizia; Casati, Silvana; Verza, Elisa; Santaniello, Enzo Tetrahedron: Asymmetry, 1995 , vol. 6, # 5 p. 1027 - 1030
Full Text: HTML
Citation Number: 4
Abstract
The regioselectivity of the Pseudomonas fluorescens (P. cepacia) lipase (PFL)-catalyzed irreversible transesterification of 2-substituted-1, 4-butanediols 1a–3a has been studied and, in the case of 3a, it has been shown that (R)-and (S)-diols are acylated with opposite regioselectivity.
Related Articles:
[Ito, Masato; Ootsuka, Takashi; Watari, Ryo; Shiibashi, Akira; Himizu, Akio; Ikariya, Takao Journal of the American Chemical Society, 2011 , vol. 133, # 12 p. 4240 - 4242]
Hydrogenolysis of succinates and glutarates
[Wojcik; Adkins Journal of the American Chemical Society, 1933 , vol. 55, p. 4943]
Concise synthesis of (+)-β-benzyl γ-butyrolactones from butynediol
[Kamlage; Sefkow; Zimmermann; Peter Synlett, 2002 , # 1 p. 77 - 80]
[Ito, Masato; Ootsuka, Takashi; Watari, Ryo; Shiibashi, Akira; Himizu, Akio; Ikariya, Takao Journal of the American Chemical Society, 2011 , vol. 133, # 12 p. 4240 - 4242]