Synthesis and Reactions of α-Dialkylaminobenzyl Butyl Ethers. Interactions with Grignard Reagents to Form Tertiary Amines1

AT Stewart Jr, CR Hauser

Index: Stewart; Hauser Journal of the American Chemical Society, 1955 , vol. 77, p. 1098,1100

Full Text: HTML

Citation Number: 32

Abstract

Several methods have been developed for the synthesis of a-dialkylaminobenzyl n-butyl ethers and select derivatives from aromatic aldehydes, aliphatic secondary amines and butanol-1. The parent compound, C~ HSCH (NR*) OGHg, was shown to be readily interconvertible with the diamine, C6H5CH (NRz)~, but not with the acetal, C~ HSCH (OC~ HQ) Z, A series of amino ethers were treated with Grignard reagents to form tertiary ...