Preparation of anti-Vicinal Amino Alcohols: Asymmetric Synthesis of D-erythro-Sphinganine,(+)-Spisulosine, and D-ribo-Phytosphingosine

EDD Calder, AM Zaed…

Index: Hubieki, M. Patricia; Gandour, Richard D.; Ashendel, Curtis L. Journal of Organic Chemistry, 1996 , vol. 61, # 26 p. 9379 - 9384

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Citation Number: 23

Abstract

... Hydrolysis of the N-acetyl group and removal of the MOM protecting group by treatment with 6 M hydrochloric acid gave (+)-spisulosine (4) in quantitative yield. ... figure Scheme 8. Synthesis of d-ribo-Phytosphingosine (3) and l-arabino-Phytosphingosine (35 ...