Journal of the American Chemical Society

Allylic Chlorides. XIV. The Preparation and Properties of cis-and trans-1, 2, 3-Trichloro-2-butene1

LF Hatch, JJ D'Amico

Index: Hatch; D'Amico Journal of the American Chemical Society, 1951 , vol. 73, p. 4393,4396

Full Text: HTML

Citation Number: 10

Abstract

The following five new compounds have been synthesized and characterized: cis-1, 2, 3- trichloro-2-butene, trans-1, 2, 3-trichloro-2-butene, cis-2, 3-dichloro-2-buten-l-ol, trans-2, 3- dichloro-2-buten-l-ol and 2, 3, 3-trichloro-l-butene. The relative reactivities of cis-and trans-1, 2, 3-trichloro-2-butene and 2, 3, 3-trichloro-l-butene have been determined for their reaction with potassium iodide in acetone, and with sodium ethoxide in ethanol. Also the relative ...