Synthesis and cure kinetics of diphenyl (diphenylethynyl) silane monomer
D Tan, Y Wang, Z Li, H Xing
Index: Tan, Dexin; Wang, Yanli; Li, Zhong; Xing, Honglong Research on Chemical Intermediates, 2013 , vol. 39, # 7 p. 3427 - 3440
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Abstract
Abstract Diphenyl (diphenylethynyl) silane ((ph–C≡ C) 2–Si–ph 2)(DPDPES) was synthesized by the Grignard reaction. The corresponding isothermal and non-isothermal cure kinetics of DPDPES were analyzed by using differential scanning calorimetry (DSC), and the molecular structure was characterized by H-NMR. The results showed that all the cure curves were typically sigmoid shape and cure reactions could be described by an ...
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