Ionic hydrogenation of α, β-unsaturated ketones with cyclohexane in the presence of aluminum halides
KY Koltunov, IB Repinskaya, GI Borodkin
Index: Koltunov; Repinskaya; Borodkin Russian Journal of Organic Chemistry, 2001 , vol. 37, # 11 p. 1534 - 1541
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Citation Number: 13
Abstract
Abstract 4-Methyl-3-penten-2-one, 3-hepten-2-one, 3-methyl-1-phenyl-2-buten-1-one, 4-(2, 4-dichlorophenyl)-, 4-(4-hydroxyphenyl)-, 4-(4-methoxyphenyl)-, 4-(2-hydroxyphenyl)-, and 4- (4-dimethylaminophenyl)-3-buten-2-ones, and 3-(4-methoxyphenyl)-1-phenyl-2-propenone react with cyclohexane in the presence of excess aluminum chloride or aluminum bromide in CH2Cl2 or CH2Br2, respectively, at room temperature to form the corresponding ...
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