Tetrahedron

Intramolecular palladium-catalyzed aryl amination and aryl amidation

JP Wolfe, RA Rennels, SL Buchwald

Index: Wolfe, John P.; Rennels, Roger A.; Buchwald, Stephen L. Tetrahedron, 1996 , vol. 52, # 21 p. 7525 - 7546

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Citation Number: 239

Abstract

Upon treatment with a palladium catalyst and a suitable base, aromatic halides undergo intramolecular substitution to form five, six, and seven-membered rings. In a similar fashion aryl halides with pendant amides or sulfonamides are cyclized to form five and six- membered rings.

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