Reaction of dialkylchloroboranes with ethyl diazoacetate at low temperatures. Facile two-carbon homologation under exceptionally mild conditions

HC Brown, MM Midland, AB Levy

Index: Journal of the American Chemical Society, , vol. 94, p. 3662 - 3664

Full Text: HTML

Citation Number: 34

Abstract

... Our recent discovery of the increased reactivity toward organic azides of dialkylchloroboranes as compared to trialkylboranes led us to investigate the related reaction between dialkylchloroboranes and ethyl diazoacetate. ... Journal of the American Chemical Society 94:lO ...

Related Articles:

In situ generated Ph 3 P (OAc) 2 as a novel reagent for the efficient acetylation of alcohols and thiols at room temperature

[Iranpoor, Nasser; Firouzabadi, Habib; Davan, Elham Etemadi Tetrahedron Letters, 2013 , vol. 54, # 14 p. 1813 - 1816]

Indanones and Indenols from 2-Alkylcinnamaldehydes via the Intramolecular Friedel− Crafts Reaction of Geminal Diacetates

[Karimi, Babak; Maleki, Jafar Journal of Organic Chemistry, 2003 , vol. 68, # 12 p. 4951 - 4954]

The addition of trichlorosilane to cyclic olefins

[Journal of the American Chemical Society, , vol. 90, p. 1871 - 1875]

The addition of trichlorosilane to cyclic olefins

[Journal of the American Chemical Society, , vol. 90, p. 1871 - 1875]

Effects of Substrate Structure on Lipase-Catalyzed Transesterification of. OMEGA.-Substituted 1-Alkanols in Organic Solvents.

[Bulletin of the Chemical Society of Japan, , vol. 67, # 11 p. 3053 - 3056]

More Articles...