Optimization of the reaction conditions in the lipase-catalyzed synthesis of structured triglycerides
U Schmid, UT Bornscheuer, MM Soumanou…
Index: Schmid; Bornscheuer; Soumanou; McNeill JAOCS, Journal of the American Oil Chemists' Society, 1998 , vol. 75, # 11 p. 1527 - 1531
Full Text: HTML
Citation Number: 87
Abstract
Abstract Structured triglycerides of the ABA-type, containing one type of fatty acid (A) in the sn-1 and sn-3 positions and a second type of fatty acid (B) in the sn-2 position of the glycerol, were synthesized using lipases. The highest yields and purities were achieved in a two-step process, where a triglyceride of the B-type was subjected to an alcoholysis reaction in an organic solvent catalyzed by sn-1, 3-regiospecific lipases yielding the corresponding ...
Related Articles:
[Kim, Young-Ah; Park, Myoung-Soon; Kim, Young Hwan; Han, So-Yeop Tetrahedron, 2003 , vol. 59, # 16 p. 2921 - 2928]
Application of chemoenzymatic hydrolysis in the synthesis of 2-monoacylglycerols
[Whitten, Kyle M.; Makriyannis, Alexandros; Vadivel, Subramanian K. Tetrahedron, 2012 , vol. 68, # 27-28 p. 5422 - 5428]
Monoacetyldiglycerides as new Ca 2+ mobilizing agents in rat pancreatic acinar cells
[Han; Cho; Kim; Seo; Moon; Jhon Bioorganic and medicinal chemistry letters, 1999 , vol. 9, # 1 p. 59 - 64]
[Martin Journal of the American Chemical Society, 1953 , vol. 75, p. 5482]
Kinetics of acyl migration in monoglycerides and dependence on acyl chainlength
[Boswinkel; Derksen; Van't Riet; Cuperus JAOCS, Journal of the American Oil Chemists' Society, 1996 , vol. 73, # 6 p. 707 - 711]