Tetrahedron letters

Aminolysis of allyl esters with bislithium aryl amides

CA Faler, MM Joullié

Index: Faler, Catherine A.; Joullie, Madeleine M. Tetrahedron Letters, 2006 , vol. 47, # 40 p. 7229 - 7231

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Citation Number: 17

Abstract

The aminolysis of allyl esters with bislithium amides is reported. Tertiary aryl amides were synthesized in a one-pot reaction with bislithium amides and a suitable electrophile in good yields. The scope of this reaction was demonstrated with a variety of anilines and aminopyridines and applied to the synthesis of triphenylmethylacetamides.

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