Tetrahedron

Self-assembly of vesicles from the stacking of a dipodal F⋯ H–N hydrogen bonded arylamide foldamer

L Wang, ZY Xiao, JL Hou, GT Wang, XK Jiang, ZT Li

Index: Wang, Lu; Xiao, Ze-Yun; Hou, Jun-Li; Wang, Gui-Tao; Jiang, Xi-Kui; Li, Zhan-Ting Tetrahedron, 2009 , vol. 65, # 51 p. 10544 - 10551

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Citation Number: 15

Abstract

In this paper, we report the synthesis and self-assembling behavior of an F⋯ H–N hydrogen bonding-induced arylamide-based dipodal foldamer. SEM, AFM, TEM, and XRD studies reveal that this preorganized oligomer stacks to form vesicles in methanol–chloroform (10– 70%) binary solvents due to the strong stacking interaction of the folded segments and the supramolecular polymeric feature of the dipodal molecule in the stacked state. In contrast, ...

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