Syntheses and Characterization of Novel trans??Bis (phosphoranido) platinum (II) Complexes: Reactions of Lithium Bis (naphth??1, 8??diyl??8??oxy) phosphoranide with …

K Kajiyama, I Sato, S Yamashita…

Index: Kajiyama, Kazumasa; Sato, Issei; Yamashita, Satoru; Miyamoto, Takeshi K. European Journal of Inorganic Chemistry, 2009 , # 36 p. 5516 - 5521

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Citation Number: 4

Abstract

Abstract The reactions of cis-PtCl 2 (PR 3) 2 (R= OPh, OMe) with 1 equiv. of lithium phosphoranide generated from a bis (naphth-1, 8-diyl-8-oxy) phosphorane lead to the formation of cis-monophosphoranido complexes with high stereospecificity. The reaction of cis-PtCl 2 (PMe 3) 2 with 1 equiv. of the lithium phosphoranide afforded a trans- monophosphoranido complex, exclusively. Hitherto unknown trans-bis (phosphoranido) ...

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