Oxidation of white phosphorus by peroxides in aqueous and alcoholic solutions: mechanistic aspects and catalytic studies

DN Akbayeva, FK Faisova, RR Abdreimova…

Index: Akbayeva, Dina N.; Faisova, Farida Kh.; Abdreimova, Rumia R.; Peruzzini, Maurizio Journal of Molecular Catalysis A: Chemical, 2007 , vol. 267, # 1-2 p. 181 - 193

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Citation Number: 7

Abstract

The oxidation of white phosphorus by hydrogen peroxide or different organic peroxides (such as tert-butyl hydroperoxide, dibenzoylperoxide, 3-chloroperoxybenzoic acid) has been studied in both aqueous and alcoholic solutions under anaerobic conditions. Depending on the reaction conditions, P (I)(hypophosphorous acid), P (III)[phosphorous acid, mono-and dialkyl (or diaryl) hydrogen phosphonates] and P (V)[phosphoric acid or trialkyl (or triaryl) ...