A study on applications of N-substituted main-chain NHC-palladium polymers as recyclable self-supported catalysts for the Suzuki–Miyaura coupling of Aryl chlorides …

B Karimi, P Fadavi Akhavan

Index: Karimi, Babak; Fadavi Akhavan, Pari Inorganic Chemistry, 2011 , vol. 50, # 13 p. 6063 - 6072

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Citation Number: 79

Abstract

The preparation and characterization of main-chain organometallic polymers (NHC-Pd MCOP) with different N-alkyl groups and their application in the Suzuki reaction of aryl chlorides is described. Using compelling evidence, such as kinetic monitoring, poisoning experiments, and average molecular weight determinations before and after catalysis, it has been rationalized that these organometallic polymers might indeed be the source of ...