A study of the influence of ionic liquids properties on the Kemp elimination reaction

F D'Anna, S La Marca, P Lo Meo…

Index: D'Anna, Francesca; La Marca, Sandra; Lo Meo, Paolo; Noto, Renato Chemistry - A European Journal, 2009 , vol. 15, # 32 p. 7896 - 7902

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Citation Number: 26

Abstract

Abstract The morpholino-induced elimination of 5-nitrobenzisoxazole into the relevant 2- cyano-4-nitrophenolate has been used as a sample reaction in order to investigate molecular properties of some room temperature ionic liquids. The kinetic study was carried out at 298 K by means of spectrophotometric measurements. Ionic liquids, which differ in both their cation and anion properties, were used as solvent systems. In particular, ...