Journal of Organometallic Chemistry

Darstellung und schwingungsspektren der trimethyl-aluminium-pseudohalogeno-komplexe [(Me3Al) 2SCN]−,[Me3AlSCN]−,[(Me3Al) 2SeCN]− und [(Me3Al) 2CN]−

F Weller, K Dehnicke

Index: Weller,F.; Dehnicke,K. Journal of Organometallic Chemistry, 1972 , vol. 36, p. 23 - 33

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Abstract

Abstract By reaction of trimethylaluminium with NMe 4 X (X SCN, SeCN, CN) the complexes listed in the title can be prepared. According to the vibrational spectra (IR and Raman) the AlMe 3 molecules are coordinated to S and Se atoms, respectively, whereas in the case of cyanide ion both C and N atoms are coordinated symmetrically to AlMe 3.