Ionic peroxide reactions. Mechanism of the reaction of peroxycarbonates with trivalent phosphorus nucleophiles
W Adam, A Rios
Index: Adam,W.; Rios,A. Journal of Organic Chemistry, 1971 , vol. 36, # 3 p. 407 - 411
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Citation Number: 5
Abstract
Results Products.-When equimolar amounts of diisopropyl peroxydicarbonate and triphenylphosphine in hexane are allowed to react at room temperature, instantaneous gas evolution is observed and a white solid precipitates. The white precipitate, formed in quantitative yield, was identified as triphenylphosphine oxide by mixture melting point with an authentic sample. By means of a gas buret it was established that 7540% carbon ...
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