New Journal of Chemistry

Carbazole functionalized luminescent silver (I), gold (I) and gold (III)–N-heterocyclic carbene complexes: a new synthetic disproportionation approach towards Au (I)– …

…, SD Adhikary, SK Seth, A Mahapatra

Index: Dinda, Joydev; Adhikary, Sirsendu Das; Seth, Saikat Kumar; Mahapatra, Ambikesh New Journal of Chemistry, 2013 , vol. 37, # 2 p. 431 - 438

Full Text: HTML

Citation Number: 18

Abstract

Synthetic, structural and photophysical properties of carbazole functionalized novel procarbenic species 1-(methyl/picolyl)-3-(N-ethylcarbazolyl)-1 H benzimidazoliumhexaflurophosphate (1 and 2) and their N-heterocyclic carbene (NHC) complexes of Ag (I)(3 and 4), Au (I)(5 and 6) and Au (III)(7 and 8) are described. According to the solid-state structures, a linear coordination geometry of Ag (I)–NHC (4) and Au (I)– ...