Experimental and computational studies of borohydride catalyzed hydrosilylation of a variety of C [double bond, length as m-dash] O and C [double bond, length as m- …

…, LS Sharninghausen, D Balcells, RH Crabtree

Index: Manas, Michael G.; Sharninghausen, Liam S.; Balcells, David; Crabtree, Robert H. New Journal of Chemistry, 2014 , vol. 38, # 4 p. 1694 - 1700

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Citation Number: 9

Abstract

Sodium borohydride and a series of related borohydrides catalyze a transition metal-free hydrosilylation of a variety of CO and CN functionalities under mild conditions. Importantly, many of these reactions are possible using the cheap and environmentally benign ...