Tetrahedron letters

The first total synthesis and structural determination of actinopyrone A

…, K Yokota, K Imamura, Y Suzuki, M Kawarasaki…

Index: Hosokawa, Seijiro; Yokota, Kazuya; Imamura, Keisuke; Suzuki, Yasuaki; Kawarasaki, Masataka; Tatsuta, Kuniaki Tetrahedron Letters, 2006 , vol. 47, # 30 p. 5415 - 5418

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Citation Number: 30

Abstract

Actinopyrone A (1) has been synthesized by using our developed remote stereoinduction, Kocienski olefination, Horner–Wadsworth–Emmons olefination, and reductive de- conjugation of the vinylpyrone. A concise method of O-methylation to obtain the γ-pyrone has also been established.