A gas kinetic study of the pyrolysis of octamethyl-1, 2-disilacyclobutane
IMT Davidson, NA Ostah, D Seyferth…
Index: Davidson, Iain M. T.; Ostah, Naaman A.; Seyferth, Dietmar; Duncan, Don P. Journal of Organometallic Chemistry, 1980 , vol. 187, # 3 p. 297 - 304
Full Text: HTML
Citation Number: 0
Abstract
Abstract Pyrolysis of octamethyl-1, 2-disilacyclobutane (I) has been shown to proceed by a unimolecular isomerisation involving a biradical which undergoes internal hydrogen- abstraction. Kinetic data were obtained for this pyrolysis and for that of the oxidation product of I, octamethyl-1, 3-disila-2-oxacyclopentane (II). A few additional experiments indicated that intermediates with π-bonds to silicon may be generated by photolysis of I. The ...
Related Articles:
Hexamethylsilirane: I. Preparation, characterization and thermal decomposition
[Seyferth, Dietmar; Annarelli, Dennis C.; Vick, Steven C.; Duncan, Don P. Journal of Organometallic Chemistry, 1980 , vol. 201, # 1 p. 179 - 195]
Hexamethylsilirane: I. Preparation, characterization and thermal decomposition
[Seyferth, Dietmar; Annarelli, Dennis C.; Vick, Steven C.; Duncan, Don P. Journal of Organometallic Chemistry, 1980 , vol. 201, # 1 p. 179 - 195]
[Kira,M.; Sakamoto,K.; Sakurai,H. Journal of the American Chemical Society, 1983 , vol. 105, p. 7469]
Hexamethylsilirane: I. Preparation, characterization and thermal decomposition
[Seyferth, Dietmar; Annarelli, Dennis C.; Vick, Steven C.; Duncan, Don P. Journal of Organometallic Chemistry, 1980 , vol. 201, # 1 p. 179 - 195]
Hexamethylsilirane: I. Preparation, characterization and thermal decomposition
[Seyferth, Dietmar; Annarelli, Dennis C.; Vick, Steven C.; Duncan, Don P. Journal of Organometallic Chemistry, 1980 , vol. 201, # 1 p. 179 - 195]