Exchange reactions of tetrathiophosphates with thiophosphoryl chloride

PS Khokhlov, GD Sokolova, VN Osipov…

Index: Khokhlov; Sokolova; Osipov; Savenkov Russian Chemical Bulletin, 1998 , vol. 47, # 9 p. 1768 - 1770

Full Text: HTML

Citation Number: 0

Abstract

Abstract Exchange reactions of tetrathiophosphates with thiophosphoryl chloride were studied. The exchange of thiol groups between compounds with tetracoordinated phosphorus centers proceeds at 150–220° C and results in the formation of dialkyl trithiochlorophosphates and alkyl (aryl) dithiodichlorophosphates or their mixtures depending on the ratio of the reagents.