Journal of Organometallic Chemistry

Reactions of group IV organometallic compounds: XXVII. The insertion reactions of benzoyl-tert-butylcarbodiimide with group IV trimethylmetallylamines and teh …

I Matsuda, K Itoh, Y Ishii

Index: Matsuda,I. et al. Journal of Organometallic Chemistry, 1974 , vol. 69, p. 353 - 359

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Citation Number: 23

Abstract

Abstract The insertion of benzoyl-tert-butylcarbodiimide with Me 3 M NMe 2 (M= Si, Ge and Sn) or (Me 3 M) 2 NMe (M= Si and Sn) is described. The pyrolyses of 11 adducts by organosilyl-and organogermyl-amines gave the corresponding Me 3 M N C N CMe 3 (M= Si and Ge) by elimination of N, N-disubstituted benzarnides.