Room??Temperature Palladium??Catalyzed Negishi??Type Coupling: A Combined Experimental and Theoretical Study

P Ribagnac, M Blug, J Villa??Uribe…

Index: Ribagnac, Philippe; Blug, Matthias; Villa-Uribe, Jose; Le Goff, Xavier-Frederic; Gosmini, Corinne; Mezailles, Nicolas Chemistry - A European Journal, 2011 , vol. 17, # 51 p. 14389 - 14393

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Citation Number: 11

Abstract

Over the past 40 years, cross-coupling reactions catalyzed by transition-metal complexes, typically those with Pd centers, have been extensively studied.[1] Their essential role in contemporary organic chemistry was recognized with the Nobel Prize in Chemistry in 2010. Csp2–Csp2 cross-coupling processes are especially relevant, as the biaryl structural is found in a wide range of organic derivatives, from supramolecular to natural products.[2] ...