Canadian Journal of Chemistry

The Reactions of Substituted Germyl-and Silylhydrazines with BX3 and CY2 Acceptor Species

LK Peterson, KI Thé

Index: Peterson,L.K.; The,K.I. Canadian Journal of Chemistry, 1972 , vol. 50, p. 562 - 566

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Citation Number: 5

Abstract

Boron trimethyl reacts with each of the organometalloid-hydrazine derivatives Me2NN (R) GeMe3 (R= H, Me, SiMe3) except Me2NN (SiMe3) GeMe3, and with Me2NNHSiMe3, forming 1: 1 adducts. With Me2NN (SiMe3) GeMe3 and BMe3, no adduct was formed even at low temperatures. On the basis of pmr spectra, the metalloid-substituted nitrogen atom rather than the terminal nitrogen, is indicated as the basic center at which adduct ...