Temperature dependence of the neutral ester hydrolysis of chloromethyl dichloroacetate in 2-butoxyethanol-water mixtures over a wide temperature range

LT Kanerva, EK Euranto

Index: Kanerva, Liisa T.; Euranto, Erkki K. Journal of the American Chemical Society, 1982 , vol. 104, # 20 p. 5419 - 5421

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Citation Number: 4

Abstract

Abstract: Rates of the water-catalyzed hydrolysis of chloromethyl dichloroacetate in 2- butoxyethanol-water mixtures in the temperature range from 2.5 to 45 OC at 2.5 “C intervals were measured conductometrically when the mole fractions of water were 0.988, 0.984, 0.981, 0.980, and 0.975. The Arrhenius plots for the reactions are S shaped when the mole fraction of water is from 0.984 to 0.975. Thus the sign of the heat capacity of activation ...