Chemical Communications

Fluorinative α-cleavage of cyclic ketoximes with diethylaminosulfur trifluoride: an efficient synthesis of fluorinated carbonitriles

M Kirihara, K Niimi, T Momose

Index: Kirihara, Masayuki; Niimi, Kanako; Momose, Takefumi Chemical Communications, 1997 , # 6 p. 599 - 600

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Citation Number: 4

Abstract

Fluorinated organic compounds are widely used in scientific and industrial fields. Since the preparative methods for organofluorine compounds remain limited to a few procedures, new fluorinating agents and methodology are required. 1 Since diethylaminosulfur trifluoride (DAST), a reagent converting aliphatic alcohols into alkyl fluorides, has been introduced into organic synthesis, 2 there have been several reports concerning new fluorinating methods ...