Coordination-driven self-assembly of cavity-cored multiple crown ether derivatives and poly [2] pseudorotaxanes
…, MM Lyndon, YR Zheng, DC Muddiman…
Index: Ghosh, Koushik; Yang, Hai-Bo; Northrop, Brian H.; Lyndon, Matthew M.; Zheng, Yao-Rong; Muddiman, David C.; Stang, Peter J. Journal of the American Chemical Society, 2008 , vol. 130, # 15 p. 5320 - 5334
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Citation Number: 82
Abstract
The synthesis of a new 120° diplatinum (II) acceptor unit and the self-assembly of a series of two-dimensional metallacyclic polypseudorotaxanes that utilize both metal–ligand and crown ether− dialkylammonium noncovalent interactions are described. Judiciously combining complementary diplatinum (II) acceptors with bispyridyl donor building blocks, with an acceptor and/or donor possessing a pendant dibenzo [24] crown-8 (DB24C8) ...
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