Sytnhèse et réactivite de quelques organozinciques dans des solvants peu courants en chimie organométallique

…, M Sebban, P Vottero, H Blancou, A Commeyras

Index: Grodin, Joseph; Sebban, Mohammed; Vottero, Philippe; Blancou, Hubert; Commeyras, Auguste Journal of Organometallic Chemistry, 1989 , vol. 362, p. 237 - 242

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Citation Number: 11

Abstract

Abstract The use of solvents strange to organometallic chemistry viz. carbonic or phosphoric esters, or sulfolane allows zinc to react with organic halides, which are unusually unreactive towards this metal. The reactions of the organozinc compounds thus synthesised (alkylzinc bromides, n-octylzinc chloride, phenylzinc iodide) have been studied.