Efficient and selective oxidative decarboxylation of arylcarboxylic acids into the corresponding aldehydes and ketones using K5CoIIIW12O40 as a green oxidant …
S Farhadi, N Ansari
Index: Farhadi; Ansari Journal of the Iranian Chemical Society, 2011 , vol. 8, # 2 p. 470 - 476
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Abstract
Abstract The oxidative decarboxylation of various α-aryl-and α, α-arylcarboxylic acids having electron-donating and electron-withdrawing groups by using a stoichiometric amount of potassium 12-tungstocobaltate (III), K 5 Co III W 12 O 40, in 50% aqueous acetonitrile solution resulted in the corresponding aldehydes and ketones in high yields within short reaction times under microwave irradiation. This transformation was also carried out under ...
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