Inorganica chimica acta

A simple route alkoxy-chloro Ti (III) and V (III) compounds

E Giannetti, E Albizzati

Index: Giannetti, E.; Albizzati, E. Inorganica Chimica Acta, 1983 , vol. 74, p. 215 - 220

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Citation Number: 5

Abstract

Abstract M (OR) n Cl 3− n compounds (M= Ti, V; R= Me, Et, Bu n; n= 1, 2) were prepared by reaction of anhydrous metal trichlorides and trialkyl orthoformates. The reaction mechanism probably involves a six-member cyclic intermediate. The alkoxy-chloro compounds have been characterized by elemental analyses, X-ray powder diffraction, infrared spectroscopy and magnetic susceptibilities.