The Journal of Organic Chemistry

Palladium-catalyzed propargylic vs. allylic alkylation

E Keinan, E Bosch

Index: Keinan, Ehud; Bosch, Eric Journal of Organic Chemistry, 1986 , vol. 51, # 21 p. 4006 - 4016

Full Text: HTML

Citation Number: 87

Abstract

The relative reactivities of allylic and propargylic acetates toward palladium (0)-catalyzed substitution by various nucleophiles were studied by using three types of model substrates:(a) monofunctional allylic and propargylic acetates with similar structural properties;(b) a bifunctional substrate containing both allyl and propargyl functionalities with no apparent interaction between them;(c) conjugated bifunctional systems, in which the ...