A new synthetic method for the preparation of amino sugars through an allyl cyanate-to-isocyanate rearrangement
II Ohtani
Index: Ichikawa, Yoshiyasu; Osada, Masafumi; Ohtani, Ikuko I.; Isobe, Minoru Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 10 p. 1449 - 1455
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Citation Number: 45
Abstract
A new approach for the synthesis of amino sugars using an allyl cyanate-to-isocyanate rearrangement has been developed. The key feature in this method involves introduction of the nitrogen substituent into the pyranose framework by [3, 3] sigmatropic rearrangement of an allyl cyanate. Subsequent functionalization of
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