Tetrahedron letters

Regioselective rhodium-catalyzed allylic alkylation with a modified Wilkinson's catalyst

PA Evans, JD Nelson

Index: Evans, P. Andrew; Nelson, Jade D. Tetrahedron Letters, 1998 , vol. 39, # 13 p. 1725 - 1728

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Citation Number: 92

Abstract

Treatment of the secondary and tertiary allylic carbonates 1 with the sodium salt of dimethyl malonate and a amount of Wilkinson's catalyst modified with a triorganophosphite, furnished the tertiary and quaternary carbon stereogenic centers 2 in high yield with excellent regioselectivity.

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