Polyhedron

Routes to titanium tetrazole complexes

MS Hill, PB Hitchcock, N Smith

Index: Hill, Michael S.; Hitchcock, Peter B.; Smith, Nikki Polyhedron, 2004 , vol. 23, # 5 p. 801 - 807

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Citation Number: 18

Abstract

The titanium tetrazole coordination complex [TiCl4·(PhCN4H) 2] has been prepared by treatment of TiCl4 with two equivalents of 5-phenyltetrazole in dichloromethane and spectroscopically and crystallographically characterised. The solid-state structure of this compound consists of six-coordinate titanium centres with cis ligated tetrazoles. The individual [TiCl4·(PhCN4H) 2] dimerise via intermolecular N⋯ H–N hydrogen bonding ...