Journal of fluorine chemistry

Fluorinated phosphorus compounds: Part 9. The reactions of bis (fluoroalkyl) phosphorochloridates with oxygen nucleophiles

CM Timperley, M Bird, MJ Waters

Index: Timperley, Christopher M.; Bird, Michael; Waters, Matthew J. Journal of Fluorine Chemistry, 2005 , vol. 126, # 6 p. 892 - 901

Full Text: HTML

Citation Number: 3

Abstract

Twenty nine bis (fluoroalkyl) phosphates (RFO) 2P (O) OR were prepared in 18–75% yield by treating phosphorochloridates (RFO) 2P (O) Cl, where RF was HCF2CH2, HCF2CF2CH2, H (CF2) 4CH2, C2F5CH2, C3F7CH2,(CF3) 2CH,(FCH2) 2CH and (CH3) 2CF3C with methanol, ethanol, propanol and isopropanol in diethyl ether in the presence of triethylamine. The bulky chloridate [(CH3) 2CF3CO] 2P (O) Cl reacted with methanol, ...