Organic Mass Spectrometry

Mass spectrometry of nitroazoles: 3—ortho effects: The loss of OH˙ and H2O from methyl substituted nitrodiazoles

W Luijten, J Van Thuijl

Index: Luijten, W. C. M. M.; Thuijl, J. van Organic Mass Spectrometry, 1982 , vol. 17, # 7 p. 299 - 303

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Citation Number: 11

Abstract

Abstract Methyl substituted nitrodiazoles which have the substituents at adjacent positions in the ring are subject to several ortho effects. Deuterium labelling of the methyl group and the mobile N-bonded hydrogen show that the loss of OH originates from the substituents. In some cases the N-bonded hydrogen atom participates also in the loss of OH and of H 2 O.