17O NMR Spectroscopic Characterization and the Mechanism of Formation of Alkyl Hydrotrioxides (ROOOH) and Hydrogen Trioxide (HOOOH) in the Low?? …
B Plesničar, J Cerkovnik, T Tekavec…
Index: Plesnicar, Bozo; Cerkovnik, Janez; Tekavec, Tomaz; Koller, Joze Chemistry - A European Journal, 2000 , vol. 6, # 5 p. 809 - 819
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Citation Number: 47
Abstract
Abstract Low-temperature ozonation of isopropyl alcohol (1 a) and isopropyl methyl ether (1 b) in [D 6] acetone, methyl acetate, and tert-butyl methyl ether at− 78 C produced the corresponding hydrotrioxides, Me 2 C (OH)(OOOH)(2 a) and Me 2 C (OMe)(OOOH)(2 b), along with hydrogen trioxide (HOOOH). All the polyoxides investigated were characterized for the first time by 17 O NMR spectroscopy of highly 17 O-enriched species. The ...
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