The Journal of Organic Chemistry

Vinyl Derivatives of Metals. XVII. Radical Additions to B-Trivinyl-N-triphenylborazine1

D Seyferth, M Takamizawa

Index: Seyferth,D.; Takamizawa,M. Journal of Organic Chemistry, 1963 , vol. 28, p. 1142 - 1144

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Citation Number: 15

Abstract

Bromotrich1oromethane.-To a mixture of 3.86 g.(0.01 mole) of 13, mp 186-187", and 5.95 g.(0.03 mole) of bromotrichloromethane in 12 g. of toluene at 80-85'was added slowly with stirring a solution of 0.12 g. of benzoyl peroxide in 5.95 g. of bromotrichloromethane. A vigorous, exothermic reaction commenced, and the temperature rose rapidly to 110'. The mixture was maintained at 110-115" for 90 min. Excess volatiles were removed at reduced ...