Chemistry–A European Journal

Ring??Rearrangement Metathesis of Nitroso Diels–Alder Cycloadducts

G Vincent, C Kouklovsky

Index: Vincent, Guillaume; Kouklovsky, Cyrille Chemistry - A European Journal, 2011 , vol. 17, # 10 p. 2972 - 2980

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Citation Number: 18

Abstract

Abstract Strained nitroso Diels–Alder bicyclo [2.2. 1] or [2.2. 2] adducts functionalized with alkene side chains of diverse length undergo a ring-rearrangement metathesis process with external alkenes and Grubbs II or Hoveyda–Grubbs II ruthenium catalysts, under microwave irradiation or classical heating, to deliver cis-fused bicycles of various ring sizes, which contain a N [BOND] O bond. These scaffolds are of synthetic relevance for the generation ...