S RN1 Reactions in the Nitrobenzo [1, 3] dioxole Series

J Meuche-Albeny, P Rathelot, MP Crozet…

Index: Meuche-Albeny; Rathelot; Crozet; Vanelle Chemistry of Heterocyclic Compounds, 2003 , vol. 39, # 8 p. 989 - 997

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Abstract

Abstract 5-Chloromethyl-6-nitrobenzo [1, 3] dioxole has been shown to react with 2- nitropropane anion to give C-alkylation by an S RN 1 mechanism. The reaction was extended to various aliphatic, cyclic, and heterocyclic nitronate anions, leading to a new series of nitrobenzo [1, 3] dioxole derivatives.