High Performance Siloxane-Containing Polymers

Y Kawakami∗, I Imae, M Oishi, M Seino…

Index: Kawakami, Yusuke; Imae, Ichiro; Oishi, Motoi; Seino, Makoto; Liu, Yang Molecular Crystals and Liquid Crystals, 2004 , vol. 415, p. 75 - 92

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Citation Number: 4

Abstract

Catalytic cross-dehydrocoupling polymerization of silane and water, and deaminative polymerisation between silanol and aminosilane are used to synthesize a variety of silicon- containing polymers with controlled structure. n-Hexylamine-2-ethylhexoate was used to catalyze silanol condensation. Among transition metal derivatives investigated, Pd2 (dba) 3is the most active catalyst for the dehydrocoupling polymerisation, and deaminative ...