Journal of organometallic chemistry

Darstellung und eigenschaften neuer monosilylcyclopentasilanderivate

PK Jenkner, E Hengge

Index: Jenkner, P. K.; Hengge, E. Journal of Organometallic Chemistry, 1992 , vol. 430, # 3 p. 259 - 267

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Citation Number: 4

Abstract

Abstract New SiMe 2 R-substituted derivatives of decamethylcyclopentasilane were prepared by different pathways. The halogen compounds where R F, Cl, Br or I exhibit a strong influence of the substituent on the physical properties of the silicon ring. Hydrolysis of the halides gives a hydroxy compound (R OH) and takes place extremely slowly, whereas the formation of polysiloxanes is favoured.