Temperature dependence of the rate constants for reaction of dihalide and azide radicals with inorganic reductants
LCT Shoute, ZB Alfassi, P Neta…
Index: Shoute, L. C. T.; Alfassi, Z. B.; Neta, P.; Huie, R. E. Journal of Physical Chemistry, 1991 , vol. 95, # 8 p. 3238 - 3242
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Citation Number: 31
Abstract
Rate constants for several reactions of inorganic radicals with inorganic reductants in aqueous solutions have been measured by pulse radiolysis as a function of temperature, generally between 5 and 75" C. The reactions studied were of the dihalide radicals, C12*-, Br2*-, and I,*-, the (SCN),'radical, and the neutral radical N3*, reacting with the substitution- inert metal complexes, Fe (CN) 6C, MO (CN)~ &, and W (CN) g4-, and with the anions SO ...
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