Australian journal of chemistry

The Molecular Structure of (Bicyclo [3.3. 1] nona-2, 6-diene) dichloropalladium (II)

J Woolcock, M Niederhut, BM Craven

Index: Woolcock, John; Niederhut, Monica; Craven Australian Journal of Chemistry, 1996 , vol. 49, # 9 p. 977 - 980

Full Text: HTML

Citation Number: 2

Abstract

Abstract The molecular structure of (C 9 H 12) PdCl 2 in solution has been studied by two- dimensional nmr spectroscopy, and the crystal structure has been determined. The spectroscopic results support earlier conclusions that in solution the Pd-diene interactions involve non-equivalent carbon atoms at each of the equivalent ethenic centres. The crystals are disordered with respect to the atoms of the eight-membered ring. The molecule has ...